22,223 research outputs found

    Role of magnesium in carbon partitioning and alleviating photooxidative damage

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    Magnesium (Mg) deficiency exerts a major influence on the partitioning of drymatter and carbohydrates between shoots and roots. One of the very early reactions of plants to Mg deficiency stress is themarked increase in the shootto- root dry weight ratio, which is associated with a massive accumulation of carbohydrates in source leaves, especially of sucrose and starch. These higher concentrations of carbohydrates in Mg-deficient leaves together with the accompanying increase in shoot-to-root dry weight ratio are indicative of a severe impairment in phloem export of photoassimilates from source leaves. Studies with common bean and sugar beet plants have shown that Mg plays a fundamental role in phloem loading of sucrose. At a very early stage of Mg deficiency, phloem export of sucrose is severely impaired, an effect that occurs before any noticeable changes in shoot growth, Chl concentration or photosynthetic activity. These findings suggest that accumulation of carbohydrates in Mg-deficient leaves is caused directly by Mg deficiency stress and not as a consequence of reduced sink activity. The role of Mg in the phloem-loading process seems to be specific; resupplying Mg for 12 or 24 h to Mg-deficient plants resulted in a very rapid recovery of sucrose export. It appears that the massive accumulation of carbohydrates and related impairment in photosynthetic CO2 fixation in Mg-deficient leaves cause an over-reduction in the photosynthetic electron transport chain that potentiates the generation of highly reactive O2 species (ROS). Plants respond to Mg deficiency stress by marked increases in antioxidative capacity of leaves, especially under high light intensity, suggesting that ROS generation is stimulated by Mg deficiency in chloroplasts. Accordingly, it has been found that Mg-deficient plants are very susceptible to high light intensity. Exposure of Mg-deficient plants to high light intensity rapidly induced leaf chlorosis and necrosis, an outcome that was effectively delayed by partial shading of the leaf blade, although the Mg concentrations in different parts of the leaf blade were unaffected by shading. The results indicate that photooxidative damage contributes to development of leaf chlorosis under Mg deficiency, suggesting that plants under high-light conditions have a higher physiological requirement for Mg. Maintenance of a high Mg nutritional status of plants is, thus, essential in the avoidance of ROS generation, which occurs at the expense of inhibited phloem export of sugars and impairment of CO2 fixation, particularly under high-light conditions

    Performance of treated and untreated asymmetric polysulfone hollow fiber membrane in series and cascade module configurations for CO2/CH4 gas separation system

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    This study investigates the effects of one-, two- and three-stage membrane system configurations in series arrangement for theCO2/CH4 separation for both untreated and treated membranes. Asymmetric polysulfone hollow fiber membranes were fabricated from 33 wt.% of polysulfone polymer using dry/wet phase inversion process. The produced membranes were characterized by pure gas permeation experiments, Differential Scanning Calorimetry (DSC), Scanning Electron Microscopy (SEM), density measurement and Thermogravimetric Analysis (TGA). For both untreated and treated membranes, the pressure-normalized flux of CO2 decreased with increasing of the membrane stages. In addition, the selectivities of asymmetric hollow fiber membrane showed a more constant trend with feed pressure. Treated membrane exhibited lower pressure-normalized flux than untreated membranes due to skin layer densification which increased the transport resistance, thus lead to the reduction in pressure-normalized fluxes. Among all the three configurations studied, two-stage membrane configuration showed the most constant trend in term of selectivity. However, three-stage cascade configuration produced the highest CO2/CH4 selectivity especially when tested at low feed pressure range. Effect of stage cut on feed pressure showed an increasing trend with increasing of CO2 and CH4 feed pressure for all configurations. This is due to the increase of the permeation driving force, which caused the passage of larger amounts of more permeable gas through the membrane. This study showed that, three-stage cascade configuration exhibited the smallest stage cut values thus produced higher purity of CO2 in permeate stream

    Leptonic Pion Decay And Physics Beyond The Electroweak Standard Model

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    The ratio of branching ratios in leptonic pion decay Rπ(Γ(πeνe))/(Γ(πμνμ))R_{\pi} \equiv (\Gamma(\pi^- \to e \nu_e))/(\Gamma(\pi^- \to \mu \nu_\mu)) is a powerfully sensitive probe of new interactions beyond the electroweak standard model. This is due to the chirality suppression of the standard model amplitude for the decay, which results in a precise prediction for the ratio, and suppressed amplitudes for new contributions to interfere with. We calculate, including QCD corrections, the contributions to RπR_{\pi} arising from a broad selection of standard model extensions to which it is sensitive, including: R-parity violating interactions in supersymmetric theories, theories with light (electroweak scale) leptoquark degrees of freedom, non-minimal models of extra doublet Higgs bosons, models in which the quarks and leptons are composite both with and without supersymmetry, and models with strong TeV scale gravitational interactions. Comparing with existing measurements of RπR_{\pi} we provide limits on each of these classes of models; our calculations also represent state of the art theoretical benchmarks against which the results from the upcoming round of leptonic pion decay experiments may be compared.Comment: 31 pages, 3 figure

    New Algebraic Formulation of Density Functional Calculation

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    This article addresses a fundamental problem faced by the ab initio community: the lack of an effective formalism for the rapid exploration and exchange of new methods. To rectify this, we introduce a novel, basis-set independent, matrix-based formulation of generalized density functional theories which reduces the development, implementation, and dissemination of new ab initio techniques to the derivation and transcription of a few lines of algebra. This new framework enables us to concisely demystify the inner workings of fully functional, highly efficient modern ab initio codes and to give complete instructions for the construction of such for calculations employing arbitrary basis sets. Within this framework, we also discuss in full detail a variety of leading-edge ab initio techniques, minimization algorithms, and highly efficient computational kernels for use with scalar as well as shared and distributed-memory supercomputer architectures
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